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Torrefaction of Napier Grass at 330°C

By:Mr Evan Wang
Position:Managing Director
Jun 05, 2024
Napier grass is a high-yielding, energy dense biomass which can be cultivated on degraded and marginal land unsuitable for normal crop farming. The torrefaction research program described in this article used a bio-engineered cultivar of Napier ‘super grass’ imported from Thailand. The grass features 70% enhanced yield, about 500+ tons/ha/year.
 
Torrefaction of napier grass can convert it to be coal-like product that features higher calorie density, hydrophobic, grindability. The physical appearance and the energy content of torrefied napier grass are similar to coal and even surpass in some instances. For example, the specific energy consumption of grinding torrefied napier grass is several times less than that of fossil coal. Thus, torrefied napier grass presents significant advantages when it’s utilized in existing combined heat and power (CHP) plants to co-fire with coal without having to change the design of CHP plants.
BioVoltz Napier Grass
 
Torrefied Napier Grass 330℃
 
We know that torrefaction occurs when thermal heat is carefully applied to napier grass under controlled thermodynamic conditions causing chemical, physical and mechanical changes to the napier grass. Biomass is mostly composed of hemicellulose, cellulose and lignin. The volatiles with low energy values are released during torrefaction process, leaving mostly cellulose and lignin. The major degradation of hemicellulose starts from around 200 ℃. Lignin starts degrading from around 275 ℃, whilst cellulose starts degrading from 330 ℃.
 
Napier grass has high cellulose content that can be used as a carbon (energy) source. Cellulose make up the largest proportion of napier grass about 50% by weight, followed by hemicelluloses which is about 30%, and lignin about 20%. To verify the performance of napier grass torrefaction at higher temperature but minimize the degrading of cellulose, SIMEC researchers launched a research program at 11th May 2024. The torrefaction research program includes the following steps:
1. Leaching of shredded napier grass;
2. Dewatering & Drying process; 
3. Torrefaction of napier grass at 275℃, 300 ℃ and 330 ℃.
4. Grinding of torrefied napier grass.
5. Pelletization treatment to make diameter 8mm bio-coal pellets.  
6. Laboratory analysis of torrefied pellets.
 
After multi times of torrefaction tests adopting a series of reaction parameters, the optimal torrefaction parameters were found by minimizing biomass weight loss and maximizing high heating value. With an increase in temperature, it was observed that torrefied napier grass turned darker from raw brown color, to blackish brown at 275℃, black at 300℃ and dark black at 330 ℃. The change in color was because of increased hemicellulose breakdown leaving higher content of carbon black. 
Napier Grass Torrefaction@330℃
 
Napier Grass Black Pellets
 
At 330 ℃ which is outside typical torrefaction temperature range, torrefied napier grass can still be pelletized to be high quality black pellets. This is of great essence as it enables easy pelletization for application in energy production. Weight loss increased when torrefaction temperature increased to  330 ℃ due to moisture removal and hemicellulose breakdown which produced H2O, CO, CO2, H2 and other hydrocarbons. But the result is still acceptable according to techno-economic assessment.
 
Please check the analysis result below issued on 19th May 2024. It can be seen that the calorific value of torrefied napier grass can reach up to 23.4 MJ/KG. Black pellets made of napier grass feature high mechanical durability and grindability, hydrophobic and low ash content. 
Moisture
Mt %
Ash Content
Ad %
Volatile Matter Content
Vad %
Fixed Carbon Content
Fcad %
St,d% High Heating Value
Qgrad Cal/g
Low Heating Value
Qnetv Cal/g
3.12 8.61 46.72 44.67 0.047 5574 5227

According to SIMEC researchers’ tests and analysis results, torrefaction of napier grass at 330 ℃ resulted in very high heating value, but without causing difficulties in the pelletizing process. High energy density black pellets can be qualified substitute for coal in power generation plants.

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